2-[2-(Trimethylsilyl)ethyl]isoindoline-1,3-dione

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2-Methoxynaphthalene-1,4-dione

The title compound, C(11)H(8)O(3), was isolated from Impatiens balsamina plants (balsam, LIB) grown in our laboratory. The two six-membered rings of the naphthalene-1,4-dione unit are coplanar [maximum deviation = 0.009 (1) Å]. The O and C atoms of the meth-oxy substituent also lie close to the naphthalene plane, with deviations of 0.0090 (2) and 0.047 (2) Å, respectively.

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2-(2-Bromoethyl)isoindoline-1,3-dione

The asymmetric unit of the title compound, C(10)H(8)BrNO(2), contains three crystallographically independent mol-ecules. Two of the N-C-C-Br side chains adopt anti conformations [torsion angles = -179.8 (5) and -179.4 (4)°] and the other is gauche [-66.5 (6)°]. The crystal structure features short Br⋯O [3.162 (5) Å] contacts, C-H⋯O hydrogen bonds and numerous π-π stacking inter-actions [centroi...

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2-(2-Iodophenyl)isoindoline-1,3-dione

In the title compound, C(14)H(8)INO(2), the dihedral angle between the isoindole ring and the phenyl ring of the 1-iodo-benzene group is 84.77 (15)°. There is a short inter-molecular I⋯O contact of 3.068 (3) Å in the crystal.

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2-[2-(Methylsulfonyl)ethyl]isoindoline-1,3-dione

In the mol-ecule of the title compound, C(11)H(11)NO(4)S, the isoindoline ring system is almost planar with a maximum deviation of 0.008 (3)Å. In the crystal structure, inter-molecular C-H⋯O inter-actions link the mol-ecules into a three-dimensional network. π-π contacts between the isoindoline rings [centroid-centroid distances = 3.592 (1) and 3.727 (1) Å] may further stabilize the structure.

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